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systems (Ikeda et al., 2007; Seki, 2007, 2004; Ikeda, 2003; Natansohn and Rochon, 2002; Sekkat and Knoll, 2002; Ichimura, 2000). This chapter focuses on recent progress in research of 2-D systems, such as monolayers and ultrathin polymer lms; the thickness of which ranges below several 10 nm. Cooperative and amplifying effects are ef ciently expressed in such 2-D thin polymer lms, where molecules are highly aligned by the con nement of the surface geometry. Topics introduced here involve surface photoalignment of mesostructured materials, preparation of surface-grafted photoresponsive polymer lms, phototriggered ef cient mass migration and its applications, and photoalignment and patterning of microphase-separated nanostructures formed by block copolymers.

Before digging into the various techniques used to display and connect to the social Web, it is important not to forget the most obvious integration tool offered: RSS feeds. In its most simple form, you ve got the RSS widget that ships with WordPress, and it easily lets you show off content from an RSS feed. And today, any social Web service, app, community, or whatever has an RSS feed for you to play with, which means that a lot of the integration of these services you may want can be done using RSS. From showing off your latest tweet to mashing up a lifestream, it s all about RSS most of the time.

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Photochromic molecule changes its polarity (dipole moment) by light, and this property has long been applied to photocontrollable wetability changes of liquids. This is still an active area of investigation (Lim et al., 2007; Ichimura et al., 2000). In cases of anisotropic liquids, namely, thermotropic LCs, the molecular orientation is readily controlled on a photoresponsive monolayer. A pioneering work was reported by Ichimura et al. (1988) (Seki et al., 1993). They showed that the trans cis photoisomerization reaction of an Az monolayer can reversibly switch the alignment of nematic LCs, and proposed a concept of command surface effect. Recent attempts by Seki and coworkers revealed that photoalignment of organized materials is not limited to typical thermotropic LCs, but a certain polymer (Fukuda et al., 2002a,b; Seki et al., 1999) and even an anisotropic structure of inorganic organic hybrid materials (Fukumoto et al., 2006, 2005; Kawashima et al., 2004, 2002) are controlled by light. The in-plane control utilizes the angular selective reaction of photoreactive units by irradiation with linearly polarized light (LPL) followed by the ordering owing to the cooperative self-assembling (Seki, 2007, 2004; Ikeda, 2003; Natansohn and Rochon, 2002; Ichimura, 2000).

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A vast amount of investigations on photoalignment of LCs has been reported during the past one and a half decades. Irradiation with LPL induces photoinduced anisotropy, in which molecules are generally oriented to an unexcitable direction, namely, perpendicular to the electric vector of the polarization direction. This effect is called photoinduced optical anisotropy (Seki, 2004; Natansohn and Rochon, 2002; Ichimura, 2000). Exposure of the 6Az10-poly(vinyl alcohol) (PVA) monolayer to LPL induces an in-plane orientation of the Az side chain orthogonal to the polarization plane of LPL. A spincast lm of poly(di-n-hexylsilane) (PDHS) is subsequently prepared onto this photooriented Az monolayer (scheme shown in Fig. 8.1, left). After

Our Employee Customer Care Group created the Best Buy forums last year, and they work with our legal team to develop our publicly posted blogging and social media guidelines (http://bbyconnect.appspot.com/ participation guidelines/). These are kind of lane bumpers with a compass north. We lay out for our employees who may not realize the signi cance of a presence that they create and maintain online. If you re an employee who works in the store, we want to just call out the fact that when you tell people you work for Best Buy, you are now placing a portion of the brand s reputation in your hands. The guidelines are not too constrictive because there is more than one way to meet and exceed customer expectations. There are going to be unique and innovated ways people can deliver something exceptional. So what metrics do you use to determine the value of such a program John admits that there are a lot of things they would like to measure but simply can t yet. How does Twelpforce compare with Dell Outlet How is positive word-of-mouth impacting store traf c nationally Is this communication tool delivering on the brand promise of helpfulness For now, the Best Buy team is tracking brand value:

Figure 8.1. Photoalignment of PDHS lm by an LPL-irradiated photoresponsive Az monolayer. Schematic illustration of the system (left) and topological AFM image (right).

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